A Self‐Complementary Assembly of Metallamacrocycles Directed by RuCl⋅⋅⋅HN Hydrogen Bonds and Its Reversible Dichotomy by Halide Anions in Solution | Zendy

Park Young Jun | Zendy; Kim JikSoo | Zendy; Youm KyoungTae | Zendy; Lee NamKyu | Zendy; Ko Jaejung | Zendy; Park Hyeseo | Zendy; Jun MooJin | Zendy

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A Self‐Complementary Assembly of Metallamacrocycles Directed by RuCl⋅⋅⋅HN Hydrogen Bonds and Its Reversible Dichotomy by Halide Anions in Solution

Author(s) -

Park Young Jun,

Kim JikSoo,

Youm KyoungTae,

Lee NamKyu,

Ko Jaejung,

Park Hyeseo,

Jun MooJin

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600154

Subject(s) - halide , dissociation (chemistry) , chemistry , hydrogen bond , ion , propane , crystallography , inorganic chemistry , molecule , organic chemistry

Back and forth : Reaction of [RuCl 2 (PPh 3 ) 3 ], 1,3‐bis(diphenylphosphino)propane, and an amido ligand yields the coordination‐driven self‐assembly of two ruthenamacrocycles through NH⋅⋅⋅ClRu, π⋅⋅⋅π, and CH⋅⋅⋅π interactions (see picture; purple Ru, green Cl, orange P, red O, blue N, gray C, white H). Reversible dissociation/association behavior of this complex in solution is controlled by halide ions.

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