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Highly Diastereoselective Synthesis of Bicyclo[3.2.1]octenones through Phosphine‐Mediated Condensations of 1,4‐Dien‐3‐ones
Author(s) -
McDougal Nolan T.,
Schaus Scott E.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600126
Subject(s) - domino , intramolecular force , phosphine , bicyclic molecule , cycloaddition , stereochemistry , wittig reaction , chemistry , computer science , combinatorial chemistry , organic chemistry , catalysis
Making rings : A highly diastereoselective synthesis of bicyclo[3.2.1]octenones from 1,4‐dien‐3‐ones occurs through a domino phosphine‐mediated formal [4+2] cycloaddition followed by an intramolecular Wittig olefination.
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