Chemoselective Benzylic CH Activations for the Preparation of Condensed N‐Heterocycles | Zendy

Ren Hongjun | Zendy; Knochel Paul | Zendy

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Chemoselective Benzylic CH Activations for the Preparation of Condensed N‐Heterocycles

Author(s) -

Ren Hongjun,

Knochel Paul

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200600111

Subject(s) - domino , ligand (biochemistry) , chemistry , chemoselectivity , combinatorial chemistry , range (aeronautics) , content (measure theory) , computer science , catalysis , medicinal chemistry , organic chemistry , materials science , mathematics , biochemistry , receptor , mathematical analysis , composite material

Buttoning up : A chemoselective domino reaction including one or two successive CH activations serves to convert a range of readily available N‐arylpyrroles into complex polycondensed N‐heterocycles. The reaction is catalyzed by Pd(OAc) 2 (5 mol %), and p ‐Tol 3 P (10 mol %) is added as the ligand (see scheme; Tol=tolyl).

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