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Hydrogen Storage in the Giant‐Pore Metal–Organic Frameworks MIL‐100 and MIL‐101
Author(s) -
Latroche Michel,
Surblé Suzy,
Serre Christian,
MellotDraznieks Caroline,
Llewellyn Philip L.,
Lee JinHo,
Chang JongSan,
Jhung Sung Hwa,
Férey Gérard
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600105
Subject(s) - hydrogen storage , metal organic framework , benzene , chromium , octahedron , porosity , intersection (aeronautics) , hydrogen , chemical engineering , chemistry , materials science , computer science , organic chemistry , engineering , crystal structure , adsorption , aerospace engineering
Large hydrogen‐storage capacity at liquid‐nitrogen temperature is exhibited by the metal–organic framework MIL‐101. In the zeotype architecture of this porous solid (see picture) each intersection of the cages is occupied by a supertetrahedron formed by trimers of chromium octahedra assembled with benzene‐1,4‐dicarboxylate ligands.