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Palladium‐Catalyzed Coupling Reactions for the Stereoselective Synthesis of Tri‐ and Tetrasubstituted Alkenes
Author(s) -
Reiser Oliver
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200600025
Subject(s) - palladium , stereoselectivity , catalysis , coupling (piping) , coupling reaction , chemistry , combinatorial chemistry , organic chemistry , materials science , metallurgy
Making advances : Efficient strategies relying on palladium‐catalyzed cross‐coupling reactions are now available for the assembly of tri‐ and tetrasubstituted alkenes with excellent stereocontrol (see scheme; Y=Hal, X=ZnHal or MgHal; other variants: Y=BR 2 , X=I).