Oxidative De‐aromatization of  para ‐Alkyl Phenols into  para ‐Peroxyquinols and  para ‐Quinols Mediated by Oxone as a Source of Singlet Oxygen | Zendy

Carreño M. Carmen | Zendy; GonzálezLópez Marcos | Zendy; Urbano Antonio | Zendy

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Oxidative De‐aromatization of para ‐Alkyl Phenols into para ‐Peroxyquinols and para ‐Quinols Mediated by Oxone as a Source of Singlet Oxygen

Author(s) -

Carreño M. Carmen,

GonzálezLópez Marcos,

Urbano Antonio

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504605

Subject(s) - aromatization , singlet oxygen , chemistry , phenols , alkyl , oxidative phosphorylation , oxygen , sodium thiosulfate , organic chemistry , catalysis , biochemistry

Easy does it : Easily handled and environmentally safe oxone generates singlet oxygen which effects the simple and selective oxidative de‐aromatization of para ‐alkyl phenols 1 into para ‐peroxyquinols 2 under very mild conditions with good to excellent yields. A one‐pot access to para ‐quinols 3 from 1 is also possible after treatment of the crude reaction mixture with sodium thiosulfate.

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