Discovery of a Family of Isopolyoxotungstates [H 4 W 19 O 62 ] 6−  Encapsulating a {WO 6 } Moiety within a {W 18 } Dawson‐like Cluster Cage | Zendy

Long DeLiang | Zendy; Kögerler Paul | Zendy; Parenty Alexis D. C. | Zendy; Fielden John | Zendy; Cronin Leroy | Zendy

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Discovery of a Family of Isopolyoxotungstates [H 4 W 19 O 62 ] 6− Encapsulating a {WO 6 } Moiety within a {W 18 } Dawson‐like Cluster Cage

Author(s) -

Long DeLiang,

Kögerler Paul,

Parenty Alexis D. C.,

Fielden John,

Cronin Leroy

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504600

Subject(s) - moiety , octahedron , cluster (spacecraft) , crystallography , trigonal crystal system , content (measure theory) , chemistry , stereochemistry , physics , computer science , crystal structure , mathematics , operating system , mathematical analysis

Caged up : A family of isopolyoxotungstate clusters of the form [H 4 W 19 O 62 ] 6− with a cluster cage (blue) identical to that of the Dawson‐type heteropolyacids (red) has been discovered. These comprise a single trigonal‐prismatic or octahedral {WO 6 } 6− moiety in place of the two heteroanions found in the Dawson structure.

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