The Phosphine‐Stabilized Gold–Arsenic Clusters [Au 19 (As n Pr) 8 (dppe) 6 ]Cl 3 , [Au 10 (As n Pr) 4 (dppe) 4 ]Cl 2 , [Au 17 (As n Pr) 6 (As 2  n Pr 2 )(dppm) 6 ]Cl 3 , and [Au 10 (AsPh) 4 (dppe) 4 ]Cl 2 : Synthesis, Characterization, and DFT Calculations | Zendy

Sevillano Paloma | Zendy; Fuhr Olaf | Zendy; Kattannek Marco | Zendy; Nava Paola | Zendy; Hampe Oliver | Zendy; Lebedkin Sergej | Zendy; Ahlrichs Reinhart | Zendy; Fenske Dieter | Zendy; Kappes Manfred M. | Zendy

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The Phosphine‐Stabilized Gold–Arsenic Clusters [Au 19 (As n Pr) 8 (dppe) 6 ]Cl 3 , [Au 10 (As n Pr) 4 (dppe) 4 ]Cl 2 , [Au 17 (As n Pr) 6 (As 2 n Pr 2 )(dppm) 6 ]Cl 3 , and [Au 10 (AsPh) 4 (dppe) 4 ]Cl 2 : Synthesis, Characterization, and DFT Calculations

Author(s) -

Sevillano Paloma,

Fuhr Olaf,

Kattannek Marco,

Nava Paola,

Hampe Oliver,

Lebedkin Sergej,

Ahlrichs Reinhart,

Fenske Dieter,

Kappes Manfred M.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504566

Subject(s) - arsenic , phosphine , octahedron , arsine , chemistry , crystallography , gold cluster , atom (system on chip) , gold compounds , inorganic chemistry , crystal structure , computational chemistry , organic chemistry , electronic structure , catalysis , computer science , embedded system , combinatorial chemistry

A heart of gold : The reaction of silylated arsenic derivatives with gold( I ) phosphine complexes produces gold–arsenic clusters, such as [Au 19 (As n Pr) 8 (dppe) 6 ] 3+ (dppe=Ph 2 P(CH 2 ) 2 PPh 2 ). This complex cation (see picture; Au gold, As blue, P violet) can be described as two crossing Au 9 As 4 chains (red and green), and contains a gold octahedron centered by a gold atom.

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