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Oxygen‐Atom Transfer between Mononuclear Nonheme Iron(IV)–Oxo and Iron(II) Complexes
Author(s) -
Sastri Chivukula V.,
Oh Kyungeun,
Lee Yoon Jin,
Seo Mi Sook,
Shin Woonsup,
Nam Wonwoo
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200504422
Subject(s) - oxidizing agent , oxygen , oxygen atom , chemistry , atom (system on chip) , inorganic chemistry , photochemistry , organic chemistry , molecule , computer science , embedded system
Completing the move : The intermetal transfer of an oxygen atom from nonheme iron(IV)–oxo to iron(II) complexes (see example, purple: Fe, red: O, blue: N, gray: C) has been unambiguously evidenced spectrophotometrically, mass spectrometrically, and electrochemically. The transfer of the oxygen atom was found to be dependent on the oxidizing power of the iron(IV)–oxo complexes.