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σ‐Donor and π‐Acceptor Stacking Interactions in a trans‐ 2 ‐ Linked C 60 –Cobalt( II ) Tetraphenylporphyrin Diad
Author(s) -
Dannhäuser Jörg,
Donaubauer Wolfgang,
Hampel Frank,
Reiher Markus,
Le Guennic Boris,
Corzilius Björn,
Dinse KlausPeter,
Hirsch Andreas
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200504383
Subject(s) - diad , moiety , stacking , porphyrin , chemistry , acceptor , triad (sociology) , stereochemistry , molecule , crystallography , photochemistry , organic chemistry , copolymer , physics , psychology , psychoanalysis , condensed matter physics , polymer
Hold me close : A trans ‐2‐linked molecular diad displays both σ‐donor and π‐acceptor interations (see picture). The crystal structure reveals linear stacking arrangements in which the fullerene moiety is located directly above the porphyrin moiety of the neighboring molecule.