A Co 2 N 2  Diamond‐Core Resting State of Cobalt( I ): A Three‐Coordinate Co I  Synthon Invoking an Unusual Pincer‐Type Rearrangement | Zendy

Fout Alison R. | Zendy; Basuli Falguni | Zendy; Fan Hongjun | Zendy; Tomaszewski John | Zendy; Huffman John C. | Zendy; Baik MuHyun | Zendy; Mindiola Daniel J. | Zendy

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A Co 2 N 2 Diamond‐Core Resting State of Cobalt( I ): A Three‐Coordinate Co I Synthon Invoking an Unusual Pincer‐Type Rearrangement

Author(s) -

Fout Alison R.,

Basuli Falguni,

Fan Hongjun,

Tomaszewski John,

Huffman John C.,

Baik MuHyun,

Mindiola Daniel J.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504343

Subject(s) - synthon , dimer , isopropyl , cobalt , chemistry , crystallography , atom (system on chip) , stereochemistry , medicinal chemistry , inorganic chemistry , computer science , organic chemistry , embedded system

Unmasking the truth : The dimer [{(μ 2 ‐PNP)Co} 2 ] (Co light blue, N dark blue, P green, C gray, only one carbon atom of the isopropyl groups shown; PNP=[N{2‐P(CHMe 2 ) 2 ‐4‐MeC 6 H 3 } 2 ] − ) contains a Co 2 N 2 diamond core and bridging PNP ligands. Upon reaction with ClCPh 3 , CO, or N 2 , rearrangement of the PNP ligands to a terminal chelating mode is observed to give four‐coordinate Co complexes such as [{(PNP)Co} 2 (μ 2 ‐N 2 )].

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