Isolation of a 1,2‐Dialuminacyclobutene | Zendy

Cui Chunming | Zendy; Li Xiaofei | Zendy; Wang Chunhua | Zendy; Zhang Jianying | Zendy; Cheng Jinpei | Zendy; Zhu Xiaoqing | Zendy

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Isolation of a 1,2‐Dialuminacyclobutene

Author(s) -

Cui Chunming,

Li Xiaofei,

Wang Chunhua,

Zhang Jianying,

Cheng Jinpei,

Zhu Xiaoqing

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504329

Subject(s) - cyclobutadiene , cyclobutene , ring (chemistry) , chemistry , isolation (microbiology) , medicinal chemistry , stereochemistry , computational chemistry , crystallography , organic chemistry , molecule , bioinformatics , biology

Aluminum siding : Reduction of Ar′AlI 2 (Ar′=2,6‐Dipp 2 C 6 H 3 , Dipp=2,6‐ i Pr 2 C 6 H 3 ) in the presence of Me 3 SiCCSiMe 3 afforded (Ar′Al) 2 (CSiMe 3 ) 2 (see picture), a dialuminum‐substituted cyclobutene analogue. The central four‐membered Al 2 C 2 ring adopts a folded geometry and is isoelectronic with aromatic cyclobutadiene dications.

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