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Organizing Supramolecular Functional Dye–Zeolite Crystals
Author(s) -
Zabala Ruiz Arantzazu,
Li Huanrong,
Calzaferri Gion
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200504286
Subject(s) - monolayer , supramolecular chemistry , acceptor , zeolite , molecule , substrate (aquarium) , materials science , crystal (programming language) , coupling (piping) , excitation , nanotechnology , chemistry , organic chemistry , catalysis , computer science , physics , oceanography , condensed matter physics , quantum mechanics , geology , metallurgy , programming language
Unidirectional antennas : Dyes in the open channels of the robust monolayers of zeolite L crystals on a glass substrate create a hierarchical order (see picture). Coupling the dye‐loaded monolayers to an external acceptor or donor stopcock dye at the channel ends enables electronic excitation energy to be trapped from donor molecules inside the crystal or to inject it to an acceptor inside the channels.