Regio‐ and Stereoselective Decarbonylative Carbostannylation of Alkynes Catalyzed by Pd/C | Zendy

Nakao Yoshiaki | Zendy; Satoh Jun | Zendy; Shirakawa Eiji | Zendy; Hiyama Tamejiro | Zendy

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Regio‐ and Stereoselective Decarbonylative Carbostannylation of Alkynes Catalyzed by Pd/C

Author(s) -

Nakao Yoshiaki,

Satoh Jun,

Shirakawa Eiji,

Hiyama Tamejiro

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504283

Subject(s) - stereoselectivity , propargyl , electrophile , aryl , chemistry , nucleophile , catalysis , alkyne , palladium , medicinal chemistry , stereochemistry , organic chemistry , alkyl

Out with the CO : The highly regio‐ and stereoselective aryl‐, alkenyl‐, and alkylstannylation of alkynes was achieved by the decarbonylative carbostannylation of propargyl 2‐furoates in the presence of Pd/C. Various functionalized alkenylstannanes were obtained that contain nucleophilic alkenylstannane and electrophilic allyl furoate moieties, which can be transformed by coupling reactions.

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