A PH‐Functionalized Polyphosphazene: A Macromolecule with a Highly Flexible Backbone | Zendy

Raab Michael | Zendy; Schick Gerold | Zendy; Fondermann Rebecca | Zendy; Dolg Michael | Zendy; Henze Wolfram | Zendy; Weynand Ulrike | Zendy; Gschwind Ruth M. | Zendy; Fischer Karl | Zendy; Schmidt Manfred | Zendy; Niecke Edgar | Zendy

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A PH‐Functionalized Polyphosphazene: A Macromolecule with a Highly Flexible Backbone

Author(s) -

Raab Michael,

Schick Gerold,

Fondermann Rebecca,

Dolg Michael,

Henze Wolfram,

Weynand Ulrike,

Gschwind Ruth M.,

Fischer Karl,

Schmidt Manfred,

Niecke Edgar

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504208

Subject(s) - polyphosphazene , macromolecule , chemistry , ab initio , polymer , computational chemistry , condensation polymer , polymer science , polymer chemistry , combinatorial chemistry , organic chemistry , biochemistry

The simplest side group : The first example of a completely H‐substituted polyphosphazene I is obtained by the polycondensation of (Me 2 N) 2 PNH 2 in solution at low temperature. NMR investigations and light‐scattering experiments substantiate the constitution of the polymer. The conformation and a reaction pathway to I are proposed on the basis of ab initio calculations.

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