A Selectivity‐Driven Supramolecular Polymerization of an AB Monomer | Zendy

Scherman Oren A. | Zendy; Ligthart G. B. W. L. | Zendy; Sijbesma Rint P. | Zendy; Meijer E. W. | Zendy

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A Selectivity‐Driven Supramolecular Polymerization of an AB Monomer

Author(s) -

Scherman Oren A.,

Ligthart G. B. W. L.,

Sijbesma Rint P.,

Meijer E. W.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200504192

Subject(s) - monomer , supramolecular chemistry , polymerization , polymer chemistry , metathesis , polymer , chemistry , stoichiometry , supramolecular polymers , polymer science , combinatorial chemistry , molecule , organic chemistry

Two become one : An AB‐type monomer containing both 2‐ureido‐4[1 H ]‐pyrimidinone and 2,7‐diamido‐1,8‐naphthyridine quadruple hydrogen‐bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self‐assembly of AA+BB‐type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations.

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