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[(C 4 H 12 N) 2 ][Zn 3 (HPO 3 ) 4 ]: An Open‐Framework Zinc Phosphite Containing Extra‐Large 24‐Ring Channels
Author(s) -
Liang Jing,
Li Jiyang,
Yu Jihong,
Chen Peng,
Fang Qianrong,
Sun Fuxing,
Xu Ruren
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200504134
Subject(s) - ring (chemistry) , chemistry , zinc , hydrothermal circulation , tetragonal crystal system , crystallography , stereochemistry , combinatorial chemistry , chemical engineering , organic chemistry , engineering , crystal structure
Hydrothermal reaction of Zn(OAc) 2 ⋅2 H 2 O and H 3 PO 3 in the presence of n ‐butylamine gives the title compound, which contains extra‐large 24‐ring channels (see framework representation). Each channel is enclosed by a tetragonal array of four 8‐ring channels interconnected by corner‐sharing 4‐ring chains through Zn‐O‐P linkages.