A Noninterpenetrating Three‐Dimensional 4 6 6 9  Iron( ii)  Coordination Polymer Built with a Trigonal‐Antiprismatic Iron( iii)  Metalloligand | Zendy

Youm KyoungTae | Zendy; Kim Min Gyu | Zendy; Ko Jaejung | Zendy; Jun MooJin | Zendy

Premium

A Noninterpenetrating Three‐Dimensional 4 6 6 9 Iron( ii) Coordination Polymer Built with a Trigonal‐Antiprismatic Iron( iii) Metalloligand

Author(s) -

Youm KyoungTae,

Kim Min Gyu,

Ko Jaejung,

Jun MooJin

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503992

Subject(s) - trigonal crystal system , boron , chemistry , crystallography , ligand (biochemistry) , rod , polymer , coordination sphere , coordination polymer , nanotechnology , topology (electrical circuits) , physics , materials science , combinatorics , crystal structure , organic chemistry , mathematics , receptor , biochemistry , medicine , alternative medicine , pathology

A second coordination sphere of six N exo atoms in a trigonal‐antiprismatic arrangement allows the metalloligand [Fe III (L) 2 ] + (red spheres, L=hydrotris(1,2,4‐triazolyl)borate) to assemble with Rh 2 (OAc) 4 linear spacers (blue rods) in an unprecedented noninterpenetrating 3D framework with 4 6 6 9 topology. The metalloligand is reduced to the iron( II ) state during the reaction by the borate ligand.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research