Premium
A Noninterpenetrating Three‐Dimensional 4 6 6 9 Iron( ii) Coordination Polymer Built with a Trigonal‐Antiprismatic Iron( iii) Metalloligand
Author(s) -
Youm KyoungTae,
Kim Min Gyu,
Ko Jaejung,
Jun MooJin
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503992
Subject(s) - trigonal crystal system , boron , chemistry , crystallography , ligand (biochemistry) , rod , polymer , coordination sphere , coordination polymer , nanotechnology , topology (electrical circuits) , physics , materials science , combinatorics , crystal structure , organic chemistry , mathematics , receptor , biochemistry , medicine , alternative medicine , pathology
A second coordination sphere of six N exo atoms in a trigonal‐antiprismatic arrangement allows the metalloligand [Fe III (L) 2 ] + (red spheres, L=hydrotris(1,2,4‐triazolyl)borate) to assemble with Rh 2 (OAc) 4 linear spacers (blue rods) in an unprecedented noninterpenetrating 3D framework with 4 6 6 9 topology. The metalloligand is reduced to the iron( II ) state during the reaction by the borate ligand.