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An Unprecedented Example of a Hetero‐trimetallic Main‐Group [L 2 Al 2 Ge 4 Li 2 S 7 ] Cluster Containing a Ge II Ge II Donor–Acceptor Bond
Author(s) -
Yang Zhi,
Ma Xiaoli,
Oswald Rainer B.,
Roesky Herbert W.,
Cui Chunming,
Schmidt HansGeorg,
Noltemeyer Mathias
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503940
Subject(s) - cluster (spacecraft) , crystallography , sulfide , chalcogen , magenta , chemistry , orange (colour) , group (periodic table) , physics , computer science , operating system , organic chemistry , food science , inkwell
Donations accepted : The reaction of [{LAl[(SLi) 2 (thf) 2 ]} 2 ] (L=HC(CMeNAr) 2 , Ar=2,6‐ i Pr 2 C 6 H 3 ) with GeCl 2 ⋅dioxane yields the novel Ge II →Ge II ‐containing hetero‐trimetallic [L 2 Al 2 Ge 4 Li 2 S 7 ] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum‐containing hetero‐trimetallic sulfide.