An Unprecedented Example of a Hetero‐trimetallic Main‐Group [L 2 Al 2 Ge 4 Li 2 S 7 ] Cluster Containing a Ge II Ge II  Donor–Acceptor Bond | Zendy

Yang Zhi | Zendy; Ma Xiaoli | Zendy; Oswald Rainer B. | Zendy; Roesky Herbert W. | Zendy; Cui Chunming | Zendy; Schmidt HansGeorg | Zendy; Noltemeyer Mathias | Zendy

Premium

An Unprecedented Example of a Hetero‐trimetallic Main‐Group [L 2 Al 2 Ge 4 Li 2 S 7 ] Cluster Containing a Ge II Ge II Donor–Acceptor Bond

Author(s) -

Yang Zhi,

Ma Xiaoli,

Oswald Rainer B.,

Roesky Herbert W.,

Cui Chunming,

Schmidt HansGeorg,

Noltemeyer Mathias

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503940

Subject(s) - cluster (spacecraft) , crystallography , sulfide , chalcogen , magenta , chemistry , orange (colour) , group (periodic table) , physics , computer science , operating system , organic chemistry , food science , inkwell

Donations accepted : The reaction of [{LAl[(SLi) 2 (thf) 2 ]} 2 ] (L=HC(CMeNAr) 2 , Ar=2,6‐ i Pr 2 C 6 H 3 ) with GeCl 2 ⋅dioxane yields the novel Ge II →Ge II ‐containing hetero‐trimetallic [L 2 Al 2 Ge 4 Li 2 S 7 ] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum‐containing hetero‐trimetallic sulfide.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research