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Gold‐ or Platinum‐Catalyzed Tandem Cycloisomerization/Prins‐Type Cyclization Reactions
Author(s) -
Barluenga José,
Diéguez Alejandro,
Fernández Amadeo,
Rodríguez Félix,
Fañanás Francisco J.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503874
Subject(s) - cycloisomerization , tandem , catalysis , prins reaction , chemistry , sequence (biology) , platinum , stereochemistry , combinatorial chemistry , organic chemistry , engineering , biochemistry , aerospace engineering
Straightforward and efficient: Functionalized eight‐membered carbocycles are easily obtained from simple allyl‐substituted 5‐hexyn‐1‐ol derivatives by a catalytic tandem sequence involving a 6‐ exo cycloisomerization followed by a Prins‐type cyclization (see scheme).
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