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Self‐Assembled Bidentate Ligands for Ru‐Catalyzed anti ‐Markovnikov Hydration of Terminal Alkynes
Author(s) -
Chevallier Floris,
Breit Bernhard
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503826
Subject(s) - denticity , markovnikov's rule , regioselectivity , ruthenium , chemistry , catalysis , hydrogen bond , combinatorial chemistry , stereochemistry , terminal (telecommunication) , crystallography , organic chemistry , molecule , computer science , crystal structure , telecommunications
In pairs : Bidentate ligands are generated by the self‐assembly of monodentate ligands through complementary hydrogen bonding. A ruthenium complex bearing such self‐assembled heterodimeric ligands is used as the catalyst in the regioselective hydration of terminal alkynes. FG=functional group, Piv=pivaloyl.