Self‐Assembled Bidentate Ligands for Ru‐Catalyzed  anti ‐Markovnikov Hydration of Terminal Alkynes | Zendy

Chevallier Floris | Zendy; Breit Bernhard | Zendy

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Self‐Assembled Bidentate Ligands for Ru‐Catalyzed anti ‐Markovnikov Hydration of Terminal Alkynes

Author(s) -

Chevallier Floris,

Breit Bernhard

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503826

Subject(s) - denticity , markovnikov's rule , regioselectivity , ruthenium , chemistry , catalysis , hydrogen bond , combinatorial chemistry , stereochemistry , terminal (telecommunication) , crystallography , organic chemistry , molecule , computer science , crystal structure , telecommunications

In pairs : Bidentate ligands are generated by the self‐assembly of monodentate ligands through complementary hydrogen bonding. A ruthenium complex bearing such self‐assembled heterodimeric ligands is used as the catalyst in the regioselective hydration of terminal alkynes. FG=functional group, Piv=pivaloyl.

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