Straightforward One‐Pot Synthesis of Trifluoromethyl Sulfonium Salts | Zendy

Magnier Emmanuel | Zendy; Blazejewski JeanClaude | Zendy; Tordeux Marc | Zendy; Wakselman Claude | Zendy

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Straightforward One‐Pot Synthesis of Trifluoromethyl Sulfonium Salts

Author(s) -

Magnier Emmanuel,

Blazejewski JeanClaude,

Tordeux Marc,

Wakselman Claude

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503776

Subject(s) - sulfonium , trifluoromethylation , reagent , trifluoromethyl , electrophile , nucleophile , aryl , chemistry , substrate (aquarium) , organic chemistry , combinatorial chemistry , salt (chemistry) , catalysis , alkyl , oceanography , geology

Mix and wait : Trifluoromethyl sulfonium salts that are able to react as reagents in the trifluoromethylation of various nucleophiles are formed in a multicomponent reaction. The desired electrophilic reagents are prepared from an aryl substrate, trifluoromethanesulfonic anhydride, and potassium trifluoromethanesulfinate in a one‐pot procedure (see scheme).

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