Functional‐Group Chemistry of Organolithium Compounds: Photochemical [2+2] Cycloaddition of Alkenyl‐Substituted Lithium Cyclopentadienides | Zendy

Paradies Jan | Zendy; Erker Gerhard | Zendy; Fröhlich Roland | Zendy

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Functional‐Group Chemistry of Organolithium Compounds: Photochemical [2+2] Cycloaddition of Alkenyl‐Substituted Lithium Cyclopentadienides

Author(s) -

Paradies Jan,

Erker Gerhard,

Fröhlich Roland

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503726

Subject(s) - cycloaddition , chemistry , lithium (medication) , functional group , yield (engineering) , organolithium compounds , carbon fibers , group (periodic table) , organic chemistry , medicinal chemistry , photochemistry , ion , catalysis , materials science , medicine , polymer , composite number , deprotonation , metallurgy , composite material , endocrinology

Li and light : Alkenyl‐substituted lithium cyclopentadienides, which are in equilibrium with the substituted lithocene anion structure 1 , undergo a photochemical [2+2] cycloaddition to yield selectively the carbon–carbon coupling product 2 . This is a rare case of organic functional‐group chemistry for a reactive organolithium compound.

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