Mixed Diketonate Thiolate Copper( I ) Precursors for Materials Synthesis: Control of Cu 2 S‐Forming Thermolysis Pathways by Manipulating Lewis Acid and Base Cluster Building Blocks | Zendy

Schneider Sven | Zendy; Roberts John A. S. | Zendy; Salata Michael R. | Zendy; Marks Tobin J. | Zendy

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Mixed Diketonate Thiolate Copper( I ) Precursors for Materials Synthesis: Control of Cu 2 S‐Forming Thermolysis Pathways by Manipulating Lewis Acid and Base Cluster Building Blocks

Author(s) -

Schneider Sven,

Roberts John A. S.,

Salata Michael R.,

Marks Tobin J.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503691

Subject(s) - lewis acids and bases , chemistry , thermal decomposition , bond cleavage , cluster (spacecraft) , copper , decomposition , sulfide , copper sulfide , organic chemistry , catalysis , computer science , programming language

Scission precision : The combination of Lewis acidic and Lewis basic building blocks in copper( I ) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu 2 S formation. After CS bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa=hexafluoroacetylacetonate).

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