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Total Synthesis of (+)‐Rugulosin and (+)‐2,2′‐ epi ‐Cytoskyrin A through Cascade Reactions
Author(s) -
Nicolaou K. C.,
Lim Yee Hwee,
Papageorgiou Charles D.,
Piper Jared L.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503678
Subject(s) - cascade , sequence (biology) , chemistry , stereochemistry , chromatography , biochemistry
The cytoskyrin cascade : The total syntheses of the bisanthraquinones 2 (+)‐2,2′‐ epi ‐cytoskyrin A (R 2 =OMe) and (+)‐rugulosin (R 2 =Me) has been achieved through a cascade sequence from anthradihydroquinone monomeric units 1 .