Premium
Chiral 3D Architectures with Helical Channels Constructed from Polyoxometalate Clusters and Copper–Amino Acid Complexes
Author(s) -
An HaiYan,
Wang EnBo,
Xiao DongRong,
Li YangGuang,
Su ZhongMin,
Xu Lin
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503657
Subject(s) - enantiopure drug , polyoxometalate , copper , enantiomer , chirality (physics) , chemistry , combinatorial chemistry , enantioselective synthesis , amino acid , polar , crystallography , stereochemistry , organic chemistry , physics , catalysis , chiral symmetry , nambu–jona lasinio model , quantum mechanics , quark , biochemistry , astronomy
A twist to the right, or to the left : Both enantiomers of a new chiral material were synthesized by a rational approach, using enantiopure proline ligands, copper cations, and Keggin polyoxometalate anions as building blocks. The compounds have open‐framework structures containing helical channels.