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Electrochemical Enol Ether/Olefin Cross‐Metathesis in a Lithium Perchlorate/Nitromethane Electrolyte Solution
Author(s) -
Miura Teppei,
Kim Shokaku,
Kitano Yoshikazu,
Tada Masahiro,
Chiba Kazuhiro
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503656
Subject(s) - nitromethane , lithium perchlorate , chemistry , lithium (medication) , electrochemistry , enol , electrolyte , olefin fiber , metathesis , deuterium , ether , inorganic chemistry , perchlorate , enol ether , organic chemistry , catalysis , ion , electrode , medicine , polymer , physics , quantum mechanics , polymerization , endocrinology
Electrolytically generated four‐membered‐ring radical‐cation intermediates are involved in the anodic olefin cross‐metathesis of enol ethers and olefins in a lithium perchlorate/nitromethane electrolyte solution (see scheme). The reaction mechanism was investigated through deuterium‐labeling studies.