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Rhodium( I ) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal→Borane Interaction
Author(s) -
Bontemps Sébastien,
Gornitzka Heinz,
Bouhadir Ghenwa,
Miqueu Karinne,
Bourissou Didier
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503649
Subject(s) - borane , rhodium , ligand (biochemistry) , derivative (finance) , chemistry , metal , stereochemistry , combinatorial chemistry , polymer chemistry , organic chemistry , catalysis , business , biochemistry , receptor , finance
To and fro : Diphosphanylborane derivative 1 behaves as a tridentate, ambiphilic ligand towards rhodium( I ) fragments (see picture). The presence of metal→borane interactions in the resulting square‐pyramidal complexes is highlighted by structural analyses and DFT calculations.