From Polymer to Size‐Defined Oligomers: An Expeditious Route for the Preparation of Chondroitin Oligosaccharides | Zendy

Lopin Chrystel | Zendy; Jacquinet JeanClaude | Zendy

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From Polymer to Size‐Defined Oligomers: An Expeditious Route for the Preparation of Chondroitin Oligosaccharides

Author(s) -

Lopin Chrystel,

Jacquinet JeanClaude

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503551

Subject(s) - chondroitin sulfate , hydrolysis , yield (engineering) , chondroitin sulphate , polymer , chemistry , chondroitin , combinatorial chemistry , computer science , organic chemistry , biochemistry , materials science , glycosaminoglycan , metallurgy

A synthetic short cut : Controlled acid hydrolysis of polymeric chondroitin sulfate affords a tailor‐made disaccharidic fragment in good yield. This compound acts as a versatile starting material for the efficient construction of size‐defined chondroitin oligosaccharides (see scheme, n =1, 2, 3, etc.) and precursors of various sulfo forms.

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