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Synthesis of Macrocyclic Aluminum–Phosphorus and Gallium–Phosphorus Compounds
Author(s) -
von Hänisch Carsten,
Stahl Sven
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503531
Subject(s) - gallium , heteroatom , phosphorus , aluminium , chemistry , ring (chemistry) , inorganic chemistry , organic chemistry
A 16‐membered ring consisting of eight aluminum or gallium atoms and eight phosphorus atoms is the central structural motif in the polycyclic compounds formed through the reaction of the diphosphanyldisiloxane O(Si i Pr 2 PH 2 ) 2 with MEt 3 (M=Al, Ga; see the heteroatom framework of the gallium compound).
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