Spherical Cluster Comprising a Four‐ and Six‐Membered‐Ring Motif | Zendy

Johnson Brian P. | Zendy; Dielmann Fabian | Zendy; Balázs Gábor | Zendy; Sierka Marek | Zendy; Scheer Manfred | Zendy

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Spherical Cluster Comprising a Four‐ and Six‐Membered‐Ring Motif

Author(s) -

Johnson Brian P.,

Dielmann Fabian,

Balázs Gábor,

Sierka Marek,

Scheer Manfred

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503511

Subject(s) - copper , magic (telescope) , tantalum , crystallography , cluster (spacecraft) , motif (music) , chemistry , ball (mathematics) , hard core , fullerene , physics , combinatorics , computer science , organic chemistry , mathematics , geometry , quantum mechanics , acoustics , programming language

Magic ball : A spherical aggregate containing a core of 32 inorganic atoms (see structure) was prepared by coordination of a cyclo ‐P 4 tantalum complex to copper( I ) chloride. The phosphorus/copper core exhibits an arrangement of alternating four‐ and six‐membered rings, which are reminiscent of the hypothetical O h ‐symmetric fullerene C 32 .

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