Separation of Hydrocarbons with a Microporous Metal–Organic Framework | Zendy

Pan Long | Zendy; Olson David H. | Zendy; Ciemnolonski Lauren R. | Zendy; Heddy Ryan | Zendy; Li Jing | Zendy

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Separation of Hydrocarbons with a Microporous Metal–Organic Framework

Author(s) -

Pan Long,

Olson David H.,

Ciemnolonski Lauren R.,

Heddy Ryan,

Li Jing

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503503

Subject(s) - microporous material , bimetallic strip , metal organic framework , adsorption , chemical engineering , block (permutation group theory) , materials science , metal , chemistry , organic chemistry , metallurgy , geometry , mathematics , engineering

Separating the wheat from the chaff : The microporous metal–organic framework (MMOF) of [Cu(hfipbb)(H 2 hfipbb) 0.5 ] is based on a bimetallic paddle‐wheel building block and comprises 1D tubular microchannels formed by the interpenetration of two identical 4 4 nets. The channels are hydrophobic and have the ideal size and shape to selectively adsorb C 2 , C 3 , and n ‐C 4 olefins and alkanes (see picture).

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