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Tribenzosubporphines: Synthesis and Characterization
Author(s) -
Inokuma Yasuhide,
Kwon Jung Ho,
Ahn Tae Kyu,
Yoo MinChul,
Kim Dongho,
Osuka Atsuhiro
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503426
Subject(s) - characterization (materials science) , boric acid , alkoxy group , condensation , ligand (biochemistry) , ring (chemistry) , condensation reaction , chemistry , combinatorial chemistry , stereochemistry , materials science , nanotechnology , physics , organic chemistry , catalysis , meteorology , biochemistry , alkyl , receptor
Keeping it in the family : A one‐pot condensation with a boric acid template leads to the synthesis of subporphineboron( III ) complexes (see example; B green, O red, N blue, C turquoise, H white), ring‐contracted congeners of porphyrins. Facile axial ligand exchange reactions provide alkoxy‐ and carboxy‐coordinated subporphyrins, which have bowl‐shaped structures with a bowl depth that depends on the axial group.