Pseudo‐Allosteric Recognition of Mandelic Acid with an Enantioselective Coordination Complex | Zendy

Heo Jungseok | Zendy; Mirkin Chad A. | Zendy

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Pseudo‐Allosteric Recognition of Mandelic Acid with an Enantioselective Coordination Complex

Author(s) -

Heo Jungseok,

Mirkin Chad A.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503343

Subject(s) - mandelic acid , enantioselective synthesis , allosteric regulation , chelation , chemistry , stereochemistry , fluorescence , molecular recognition , combinatorial chemistry , receptor , catalysis , biochemistry , organic chemistry , molecule , physics , quantum mechanics

The weak‐link approach is used to synthesize a four‐coordinate Cu I complex for the chiral recognition of mandelic acid. The chelation through 2,2′‐bipyridine in a reaction that concomitantly breaks weak CuS links and opens the condensed structure into a 27‐membered macrocycle switches on the complex so it acts as an enantioselective fluorescent receptor.

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