Formation of a Dicyanotriorganophosphorane from the Reaction of Triphenylphosphane with Phenylselenocyanate | Zendy

Barnes Nicholas A. | Zendy; Godfrey Stephen M. | Zendy; Halton Ruth T. A. | Zendy; Law Suzanna | Zendy; Pritchard Robin G. | Zendy

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Formation of a Dicyanotriorganophosphorane from the Reaction of Triphenylphosphane with Phenylselenocyanate

Author(s) -

Barnes Nicholas A.,

Godfrey Stephen M.,

Halton Ruth T. A.,

Law Suzanna,

Pritchard Robin G.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200503335

Subject(s) - mechanism (biology) , chemistry , reaction mechanism , group (periodic table) , stereochemistry , catalysis , physics , organic chemistry , quantum mechanics

A glimpse of the elusive : A Group 15 triorganodicyanide has been prepared and crystallographically characterized for the first time. The reaction of phenylselenocyanate with triphenylphosphane affords a facile route to the elusive dicyanotriorganophosphorane Ph 3 P(CN) 2 . The complex reaction mechanism also results in formation of the diiminophosphorane Ph 3 PNC(CN) 2 C(CN) 2 NPPh 3 .

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