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Towards the Determination of the Absolute Configuration of Complex Molecular Systems: Matrix Isolation Vibrational Circular Dichroism Study of ( R )‐2‐Amino‐1‐propanol
Author(s) -
Tarczay György,
Magyarfalvi Gábor,
Vass Elemér
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503319
Subject(s) - vibrational circular dichroism , absolute configuration , circular dichroism , matrix isolation , conformational isomerism , hydrogen bond , molecule , intermolecular force , chemistry , infrared spectroscopy , 1 propanol , spectroscopy , propanol , matrix (chemical analysis) , crystallography , stereochemistry , ethanol , organic chemistry , physics , chromatography , quantum mechanics
Molecular freeze‐frame : ( R )‐2‐Amino‐1‐propanol was used as an example to show that matrix isolation vibrational circular dichroism spectroscopy is a useful method for the determination of the absolute configuration of molecules with multiple conformers that are capable of strong intermolecular interactions, especially hydrogen bonds.