Premium
Copper‐in‐Charcoal (Cu/C): Heterogeneous, Copper‐Catalyzed Asymmetric Hydrosilylations
Author(s) -
Lipshutz Bruce H.,
Frieman Bryan A.,
Tomaso Anthony E.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503149
Subject(s) - copper , charcoal , catalysis , chemistry , hydride , organic chemistry , metal
Asymmetric copper chemistry … done heterogeneously? It's doable: Copper‐in‐charcoal (Cu/C) is introduced as an easily prepared catalyst that is readily converted in situ into a nonracemically ligated form of copper hydride that effects asymmetric hydrosilylations. DTBM=3,5‐di‐ tert‐ butyl‐4‐methoxydiphenylphosphinyl.