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Bi‐3 H ‐diazirin‐3‐yls as Precursors of Highly Strained Cycloalkynes
Author(s) -
AlOmari Mohammad,
Banert Klaus,
Hagedorn Manfred
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503124
Subject(s) - cycloaddition , reagent , chemistry , transformation (genetics) , combinatorial chemistry , chemical engineering , organic chemistry , catalysis , engineering , biochemistry , gene
No reagents and very mild conditions are required for the transformation of isolable precursors 3 into highly strained cycloalkynes 4 (cycloheptyne, cyclohexyne, norbornyne), which can be trapped by cycloaddition reactions.