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Lithium Alkoxide {Li 4 O 4 } Cubanes Bridged by Rhodium–Quinonoid Organometalloligands
Author(s) -
Son Seung Uk,
Reingold Jeffrey A.,
Kim Sang Bok,
Carpenter Gene B.,
Sweigart Dwight A.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503050
Subject(s) - rhodium , alkoxide , chemistry , lithium (medication) , organic chemistry , catalysis , medicine , endocrinology
Joining the cubes : The linking of lithium {Li 4 O 4 } cubanes by the bifunctional organometalloligand [(η 4 ‐quinone)Rh(cod)] − (cod=cyclooctadiene) results in an unprecedented doubly bridged motif. The dimeric assembly features cubane units that are connected by a transition‐metal complex and that incorporate a quinone oxygen atom at one of the corners.
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