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A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity
Author(s) -
Dybtsev Danil N.,
Nuzhdin Alexey L.,
Chun Hyungphil,
Bryliakov Konstantin P.,
Talsi Evgeniy P.,
Fedin Vladimir P.,
Kim Kimoon
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200503023
Subject(s) - enantioselective synthesis , sorption , microporous material , catalysis , chemoselectivity , chemistry , metal organic framework , organic chemistry , porosity , adsorption
A handy approach : A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal–organic microporous framework. The material exhibits size‐ and enantioselective guest‐sorption properties (see picture), as well as remarkable catalytic activity with size‐ and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides.