The Chlorination of the [Al 13 ] −  Cluster and the Stepwise Formation of Its Intermediate Products, [Al 11 ] − , [Al 9 ] − , and [Al 7 ] − : A Model Reaction for the Oxidation of Metals? | Zendy

Burgert Ralf | Zendy; Schnöckel Hansgeorg | Zendy; Olzmann Matthias | Zendy; Bowen Kit H. | Zendy

Premium

The Chlorination of the [Al 13 ] − Cluster and the Stepwise Formation of Its Intermediate Products, [Al 11 ] − , [Al 9 ] − , and [Al 7 ] − : A Model Reaction for the Oxidation of Metals?

Author(s) -

Burgert Ralf,

Schnöckel Hansgeorg,

Olzmann Matthias,

Bowen Kit H.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502957

Subject(s) - fourier transform ion cyclotron resonance , chemistry , cluster (spacecraft) , mass spectrometry , ion , inorganic chemistry , computer science , organic chemistry , operating system , chromatography

Watch your step! The individual steps during the chlorination of [Al 13 ] − clusters via [Al 11 ] − , [Al 9 ] − , and [Al 7 ] − intermediates (see picture) can be “visualized” by means of Fourier transform ion cyclotron resonance (FT‐ICR) mass spectrometry. The reaction can be interpreted as a model reaction for the chlorination of bulk aluminum.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research