Direct Phenol Synthesis by Selective Oxidation of Benzene with Molecular Oxygen on an Interstitial‐N/Re Cluster/Zeolite Catalyst | Zendy

Bal Rajaram | Zendy; Tada Mizuki | Zendy; Sasaki Takehiko | Zendy; Iwasawa Yasuhiro | Zendy

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Direct Phenol Synthesis by Selective Oxidation of Benzene with Molecular Oxygen on an Interstitial‐N/Re Cluster/Zeolite Catalyst

Author(s) -

Bal Rajaram,

Tada Mizuki,

Sasaki Takehiko,

Iwasawa Yasuhiro

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502940

Subject(s) - zeolite , catalysis , benzene , phenol , chemistry , selectivity , oxygen , molecular oxygen , chemical engineering , inorganic chemistry , photochemistry , organic chemistry , engineering

Remarkable selectivity (88 % in the steady‐state reaction and 94 % in the pulse reaction) is observed in the direct synthesis of phenol from benzene with molecular oxygen over a Re/zeolite catalyst prepared by chemical‐vapor deposition. The novel interstitial‐N/Re clusters are formed with NH 3 and are essential for the activity in the selective oxidation reaction.

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