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Ordered Nanostructures from the Self‐Assembly of Reactive Coil–Rod–Coil Molecules
Author(s) -
Jin Long Yi,
Bae Jinyoung,
Ryu JaHyoung,
Lee Myongsoo
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502911
Subject(s) - nanoreactor , photopolymer , electromagnetic coil , self assembly , materials science , supramolecular chemistry , nanofiber , nanostructure , molecule , nanotechnology , coiled coil , polymerization , chemistry , nanoparticle , composite material , polymer , physics , organic chemistry , quantum mechanics , biochemistry
Keeping in shape : Polymerizable coil–rod–coil molecules self‐organize into 2D columnar and 3D bicontinuous liquid crystals whose supramolecular architectures and lattice dimensions are preserved upon photopolymerization (see picture). Nanofibers resulting from the photopolymerization of the 2D structures are utilized as nanoreactors for Suzuki coupling reactions.