Unusual Structure and Reactivity of a Homoleptic “Super‐Ate” Complex of Iron: Implications for Grignard Additions, Cross‐Coupling Reactions, and the Kharasch Deconjugation | Zendy

Fürstner Alois | Zendy; Krause Helga | Zendy; Lehmann Christian W. | Zendy

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Unusual Structure and Reactivity of a Homoleptic “Super‐Ate” Complex of Iron: Implications for Grignard Additions, Cross‐Coupling Reactions, and the Kharasch Deconjugation

Author(s) -

Fürstner Alois,

Krause Helga,

Lehmann Christian W.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502859

Subject(s) - homoleptic , chemistry , reactivity (psychology) , cyan , alkyl , methyllithium , stereochemistry , magenta , coupling reaction , molecule , computational chemistry , organic chemistry , catalysis , metal , materials science , art , medicine , alternative medicine , pathology , visual arts , composite material , inkwell

The additional molecule of methyllithium present in [(Me 4 Fe)(MeLi)][Li(OEt 2 )] 2 ( 1 ), the first structurally characterized ate complex of Fe II bearing only alkyl substituents without any further stabilizing ligands (see picture: Fe: magenta; Li: cyan; O: red; C and H: gray), is a particularly remarkable structural feature and contributes to the fascinating reactivity profile of 1 in the title reactions.

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