Acid‐Induced Conversions in Open‐Framework Semiconductors: From [Cd 4 Sn 3 Se 13 ] 6−  to [Cd 15 Sn 12 Se 46 ] 14− , a Remarkable Disassembly/Reassembly Process | Zendy

Ding Nan | Zendy; Kanatzidis Mercouri G. | Zendy

Premium

Acid‐Induced Conversions in Open‐Framework Semiconductors: From [Cd 4 Sn 3 Se 13 ] 6− to [Cd 15 Sn 12 Se 46 ] 14− , a Remarkable Disassembly/Reassembly Process

Author(s) -

Ding Nan,

Kanatzidis Mercouri G.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502787

Subject(s) - ion exchange , crystallography , semiconductor , physics , chemistry , ion , computer science , optoelectronics , organic chemistry

Swapping structures and cations : In an acid‐induced 3D‐to‐3D transformation at room temperature, K 6 Cd 4 Sn 3 Se 13 is converted into K 14− x H x Cd 15 Sn 12 Se 46 . The [Cd 15 Sn 12 Se 46 ] 14− framework, which contains a tunnel network of accessible cages of labyrinthine complexity (see picture), is highly robust, acid resistant, and has excellent ion‐exchange properties.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research