Catalytic Enantioselective Hydrogenolysis of [Cr(CO) 3 (5,8‐Dibromonaphthalene)] | Zendy

Kündig E. Peter | Zendy; Chaudhuri Piyali Datta | Zendy; House David | Zendy; Bernardinelli Gérald | Zendy

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Catalytic Enantioselective Hydrogenolysis of [Cr(CO) 3 (5,8‐Dibromonaphthalene)]

Author(s) -

Kündig E. Peter,

Chaudhuri Piyali Datta,

House David,

Bernardinelli Gérald

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502688

Subject(s) - hydrogenolysis , phosphoramidite , enantioselective synthesis , catalysis , yield (engineering) , aryl , chemistry , bromine , naphthalene , ligand (biochemistry) , organic chemistry , materials science , alkyl , dna , biochemistry , receptor , oligonucleotide , metallurgy

Split and run : A study of the asymmetric hydrogenolysis of an aryl‐carbon–bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new bulky phosphoramidite ligand to yield the product in highly enantiomerically enriched form (see scheme).

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