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Catalytic Enantioselective Hydrogenolysis of [Cr(CO) 3 (5,8‐Dibromonaphthalene)]
Author(s) -
Kündig E. Peter,
Chaudhuri Piyali Datta,
House David,
Bernardinelli Gérald
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502688
Subject(s) - hydrogenolysis , phosphoramidite , enantioselective synthesis , catalysis , yield (engineering) , aryl , chemistry , bromine , naphthalene , ligand (biochemistry) , organic chemistry , materials science , alkyl , dna , biochemistry , receptor , oligonucleotide , metallurgy
Split and run : A study of the asymmetric hydrogenolysis of an aryl‐carbon–bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new bulky phosphoramidite ligand to yield the product in highly enantiomerically enriched form (see scheme).