Aqueous Fe IV O: Spectroscopic Identification and Oxo‐Group Exchange | Zendy

Pestovsky Oleg | Zendy; Stoian Sebastian | Zendy; Bominaar Emile L. | Zendy; Shan Xiaopeng | Zendy; Münck Eckard | Zendy; Que Lawrence | Zendy; Bakac Andreja | Zendy

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Aqueous Fe IV O: Spectroscopic Identification and Oxo‐Group Exchange

Author(s) -

Pestovsky Oleg,

Stoian Sebastian,

Bominaar Emile L.,

Shan Xiaopeng,

Münck Eckard,

Que Lawrence,

Bakac Andreja

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502686

Subject(s) - aqueous solution , radical , chemistry , mössbauer spectroscopy , group (periodic table) , content (measure theory) , spectroscopy , absorption spectroscopy , analytical chemistry (journal) , crystallography , physics , organic chemistry , mathematics , quantum mechanics , mathematical analysis

A combination of techniques (Mössbauer and X‐ray absorption spectroscopy, H 2 18 O exchange experiments, and DFT calculations) has shown that the reaction of [Fe(H 2 O) 6 ] 2+ with ozone generates [(H 2 O) 5 Fe IV O] 2+ (see calculated structure). The oxidation of selected substrates with [(H 2 O) 5 Fe IV O] 2+ yields unique products that are different from those generated in the Fenton reaction or derived from HO . radicals.

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