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Regiospecific Ligand Oxygenation in Iron Complexes of a Carboxylate‐Containing Ligand Mediated by a Proposed Fe V –Oxo Species
Author(s) -
Nielsen Anne,
Larsen Frank B.,
Bond Andrew D.,
McKenzie Christine J.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502656
Subject(s) - ligand (biochemistry) , chemistry , carboxylate , nitrogen atom , atom (system on chip) , nitrogen , oxygen atom , crystallography , carbon fibers , combinatorial chemistry , stereochemistry , organic chemistry , molecule , materials science , ring (chemistry) , computer science , biochemistry , receptor , composite number , composite material , embedded system
Mimicked : Through biomimetic iron activation of peroxides (H 2 O 2 or t BuOOH), the shown N 4 O ligands in their iron( III ) complexes can be oxygenated selectively at either an aromatic carbon atom or an aliphatic nitrogen atom.