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Extending Mechanistic Routes in Heterazolium Catalysis–Promising Concepts for Versatile Synthetic Methods
Author(s) -
Zeitler Kirsten
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502617
Subject(s) - enantioselective synthesis , carbene , catalysis , combinatorial chemistry , chemistry , organocatalysis , carboxylate , broad spectrum , nanotechnology , computer science , organic chemistry , materials science
A broad spectrum of valuable cyclic and acyclic products are available in diastereo‐ and/or enantioselective form by sustainable, organocatalytic processes like the heterazolium‐catalyzed transformations shown in the scheme. The carbene‐mediated generation of activated carboxylate intermediates provides new possibilities for the straightforward synthesis of multifunctionalized compounds.