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Synthesis of Borirenes by Photochemical Borylene Transfer from [(OC) 5 MBN(SiMe 3 ) 2 ] (M=Cr, Mo) to Alkynes
Author(s) -
Braunschweig Holger,
Herbst Thomas,
Rais Daniela,
Seeler Fabian
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502524
Subject(s) - chemistry , irradiation , photochemistry , physics , nuclear physics
Light movements : Irradiation of terminal borylene complexes [(OC) 5 MBN(SiMe 3 ) 2 ] (M=Cr, Mo) at room temperature in the presence of alkynes allows access to various substituted borirenes—an unprecedented borylene transfer to main‐group‐element substrates (see scheme; B red, C white, N blue, Si yellow).